UNIVERSITAS PADJADJARANDepartment of Chemistry Indonesia

R04 / Controlling molecular uptake and selectivity

Selective Adsorption & Separation

We investigate porous inorganic and hybrid materials for selective uptake from liquids and separation of gas mixtures. Our research connects pore structure, composition, and surface chemistry with adsorption capacity, molecular discrimination, and material recovery, including MOFs and waste-derived magnetic adsorbents.

People in this direction

The questions behind the materials.

Selective adsorption and separation exploit differences in how molecules interact with a material. This direction focuses on the relationships between pore structure, surface chemistry, composition, and uptake behaviour in liquid and gas systems.

Our work includes metal–organic frameworks and other inorganic or hybrid adsorbents. Published studies cover aqueous synthesis of ZIF-14 and rice husk ash-derived magadiite–magnetite and carbon–magnetite composites for anionic surfactant adsorption. Current member topics include magnetic magadiite-based nanocomposites from rice husk ash for surfactant removal and porous alumina, carbon, and MOF-based adsorbents for radioisotope production, radionuclide separation, and purification.

For adsorption from liquids, we examine uptake and the influence of material characteristics and operating conditions. For gas separation, the focus is on material–molecule interactions that favour selected components of a mixture. Material recovery and reuse are considered where relevant to the system, including magnetic recovery of composite adsorbents.

The central question is how material design can improve useful uptake and discrimination between molecules. Pollutant removal connects this direction with Environmental Remediation, while the emphasis here is on capture, selectivity, and separation. MOF synthesis provides a materials foundation and is distinguished from demonstrations of a specific separation application.

Research question

How do pore structure and surface chemistry govern molecular uptake, selectivity, and separation?

Our objective: Relate composition and pore properties to uptake and selectivity. Investigate MOFs for liquid adsorption and gas separation. Evaluate recoverable adsorbents and operating conditions relevant to each system.

Approaches in this direction

Porous-material synthesisPore & surface modificationLiquid-phase adsorptionGas separationAdsorbent recovery

Materials & systems

Metal–organic frameworksZIF-14Magadiite–magnetiteCarbon–magnetiteZeolite-based adsorbents

Keywords

Selective adsorptionGas separationMetal–organic frameworksPorous materialsSurface chemistryMagnetic recovery

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